I have been to Sedona. Schelbey Hill Road in Sedona has some very interesting mountains, but make sure you have a high clearence vehicle as the road is very rugged.
Another fun location is going down to oak creek to get shots of Cathedral Rock with the creek in the foreground. To get to the creek, head south on 179 to the town of Oak creek. When you get into town, turn right (northwest) on Green Valley Road (I am not sure about the name). This road will take you all the way to the river. From what I remember you will have to park in the parking lot about 1 block from the river but you can drive all the way down to an overlook near the river to scope things out. You can walk down to the river and look left and you should see a small bridge. From here you can take the classic "Cathedral Rock with Oak Creek in the foreground shot.
Another possibility is staying on the south of the creek and take the trail that heads toward Cathedral rock to the east. Walk about 2 blocks and then find a path toward the creek and you should be able to find a different framing of "Cathedral rock and river".
If you get real adventurous, you can go back to the trail and follow the signs to the top of Cathedral rock. I didn't have a chance to do this last time I went but it is on my list! Enjoy your trip!
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