The best place to learn LF is on this site. There's lots of stuff to see. As you know, you also have the opportunity to ask questions. The two make a powerful combination for learning.
I agree with Christopher on starting out with color slides or negs. I would say negs, because you have a lot more latitude. Do you have a color "u-develop" in your area? If so, it can be an excellent resource in which to develop your own prints. We have one in Portland, and they help determine exposure, color correction, etc. This type of system works very well for beginners.
You can get some very nice B&W results from Type 55 negatives. But, you must expose them at about 30 ASA.
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