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I'm a fairly heavy user of Velvia, and stock all three. The only other color film I stock and shoot is Provia 100F and Fuji Tungsten 64. My opinions of the different three Velvias (only by personal feelings, with no data for backup):
Velvia 50: Best for general colors in excellent lighting. My go-to Velvia for sunrise and sunsets and colorful scenes. Only use it when light conditions are perfect. Excellect rendition of blues and greens... a bit too hard saturation pushes on reds and yellows.
Velvia 100: I use it when light conditions aren't quite as perfect (but still doesn't do well with harsh lighting). Saturation kicks not quite as hard as Velvia 50, especially in reds and yellows.
Velvia 100F: Dreadful for green scenes (the green-tones are off-yellow). The best film there is for predominantly blue scenes. More docile than V50 for reds and yellows. I never use it for forest-type shots.
When lighting is perfect and/or I want a saturation boost, I usually shoot Velvia 50 or 100. When lighting is perfect and the scene is heavy in blues I shoot Velvia 100F. For most other conditions I personally reach for Provia. I've tried Astia and like it for pastel-toned scenes, but have never developed a heavy liking for it in other conditions.
Disclaimer: Personal opinions all the above.....
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