Velvia in itself doesn't require any special filters... especially since I gather you are scanning films, and it's easier to tweek colors a bit in PhotoShop than in surmising what color-enhancer/corrector to use . I find myself toning down sat levels in reds and yellows in editing when shooting Velvia films.
Reciprocity isn't much of a problem as long as times don't get excessively long (exposure times measured in minutes not seconds) and any slight color shift can be corrected in editing. I would suggest for very long exposures looking towards another film (Provia 100F works very nicely for very long exposures... even times measured in hours).
As for the questions about the circular polarizer: No, a linear polarizer is all that's needed for LF. But... I still use circular polarizers so they can be used on all cameras. No sense in having an expensive filter delegated only for LF, and having to buy a replacement if you should buy a different camera later or have other cameras that you use.
If you're looking to build a filter kit and starting from scratch, the ones to consider buying first (in my opinion):
a) A high-grade polarizer (circular), and not a bargain one. Quality of polarizing filters are very evident in final results.
b) Several Gradiant ND's (one hard, one soft... 2-stop graduations on both to start a kit).
c) At least one ND (2-stop if only buying one and not a kit) for shooting those waterfalls if you are looking for that milky look.
d) An 81B warming filter to warm scenes when the light is too cool. Also works great in conjunction with a polarizer to give warmth to an image.
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