Pyrocat-HD is definitely a good developer for alternative printing. The stain gives a boost in contrast and sharpness is excellent.
Basically I don't know if it is possible to make a negative that will print well in both vandyke and regular silver printing. If you develop long enough to get the contrast you need for vandyke you will have to print in silver with a very low contrast filter. That may work, but the requirements for the two processes are so different you would probably get better results optimizing your development for one or the other.
Sandy King
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