In the Luminous Landscape Lightroom tutorial video Jeff Schewe mentions that even Photoshop folk say that TIFF is most archival format because the code is publically documented whereas PSD is proprietary. Of course, there's probably other concerns besides file format in regards to being able to open legacy files in years to come.
PSD is nice but TIFFs are more generic you can placed layered TIFFs into Quark without a plugin. Well, that may have changed in v7, can't remember.
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