The color selection methods, if the landscape horizon and the sky are different colors, is the best way to go. If you're going to do everything manually, then if there are sharp lines, such as a mountain or roof edge, use the pen tool. If there's fuzziness on the horizon, and color tools don't work, then use an appropriate paint brush in Quick Mask mode. Quick Mask mode is very good for refining a mask that you made with other methods. Please don't use the lasso or magic wand tools. It is difficult to be precise with those tools.
Also, don't use the eraser tool. Instead, use a layer mask and paint in black where you don't want the layer to show through. You can always redo it, which you can't always do with the eraser tool.
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