This has been a good discussion here.
The concerns expressed about selenium toner disposal could be addressed to a very large extent by how one uses selenium toner. I'm mostly referring to Kodak Rapid Selenium Toner (KRST) here, so other variant toners might need other procedures. I'm no chemist, so the chemists out there could clarify and correct me on this, but my understanding on the use of selenium toner is that if you keep your toner alkaline and keep it clean and filtered, it should last a very very long time. If I get it right, selenium toner degrades quite fast when allowed to become acidic.
How you keep KRST alkaline is to get acid fix out of your system entirely, or to wash your prints far enough to neutralize them before putting them into the toner, or to neutralize the acid fix by bathing the prints in sulfite based hypo clearing agents before toning. I wash and dry my prints before deciding which I want to tone, so they are pretty neutral. Regardless, I first bathe them in a sulfite bath before toning. The sulfite renders them mildly alkaline. My toner stays very clean without even needing filtration.
The idea that one should add HCA to toner has been said to have the weakness that the sulfite will get old before the selenium toner, and that it's better to pre-treat than to mix KRST and HCA together.
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