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Thread: difference between monohydrated and anhydrous

  1. #1

    difference between monohydrated and anhydrous

    Hi,

    I finally ran out of my stock of Kodak Sodium Carbonate(don't remember whether it's mono or anhydrous), while trying to order them from Photographer's Formulary, I found they have both. Can one be use for the other? what is the difference between them?

    Artcraft just carry one of them, the mono version.

    thanks in advance

    Robert

  2. #2

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    Re: difference between monohydrated and anhydrous

    The monohydrate contains one molecule of water per molecule of sodium carbonate. I can't see that it would make much difference in actual use.

  3. #3

    Re: difference between monohydrated and anhydrous

    The Beer formula calls for monohydrated, does that mean the monohydrated is not completely desiccated?

  4. #4

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    Re: difference between monohydrated and anhydrous

    No, it's dry and crystallized, but it has one water of hydration. Normally, you'd just account for the extra water of hydration in weighing out chemical (it weighs a little more with the H2O molecule) for precise uses, but I highly doubt it would make the least bit of difference in your formula. But I'm a biologist, so I fully expect a smackdown from a chemist.

  5. #5

    Re: difference between monohydrated and anhydrous

    well, I am just a darkroom alcoholic so it's deserving to get a full smack down from both the biologist and chemist

    Thanks for the clarification, I'll just go with what ever is the least expensive

    Robert

  6. #6
    IanG's Avatar
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    Re: difference between monohydrated and anhydrous

    Actually the Beers formlula calls for anhydrous Sodium Carbonate, it's just hat some US publications convert and list as Monohydrate instead. Others (Anchell) list it with Potassium Carnbonate but that give a slight tone change.

    The ratio of Monohydrate to Anhydrous is approx 1.17 : 1 The anhydrous form is most coomon, (in Europe) followed by the crystalline form.

    Ian

  7. #7

    Re: difference between monohydrated and anhydrous

    A significant difference between the two is that the monohydrated form dissolves much quicker. The anhydrous form can be substituted for the monohydrated form: as noted above, 1 part of the anhydrous form = 1.17 parts of the monohydrated form. To illustrate: Ansco 103 calls for 78.0 grams of the monohydrate. When using the anhydrous form instead, use (78.0/1.17) ~ 66.7 grams.

    N. Riley
    http://normanrileyphotography.com

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