Thanks for the replies, everyone. The envelopes they're currently in are
this style, the sort that was commonplace back in the day. My prints are a mixture of qualities, glossy and matte, from the 50s to 2000s.
I'm from the UK, where unfortunately the archiving options seem to be very high-end and museum-focused. I don't see many shops catering to amateurs and family archiving projects, thus why I'm focusing on materials rather than specialist products.
What do we think about the prints 'breathing'? Have any of you encountered issues with prints being kept in air-tight packaging?
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