Results 1 to 7 of 7

Thread: Please help "Sodium Metaborate" alternative

  1. #1

    Join Date
    Mar 2019
    Location
    Egypt, Suez
    Posts
    4

    Please help "Sodium Metaborate" alternative

    Hello every one,

    Good day to you all,
    I have a big problem and I need help, I have been using Kodak DK-50 for a while now and I can't get any new supplies from it, I tried to get some from outside Egypt and the airport customs in Egypt blocked it from entering the country, right now I can't work and me and my family depend on my work.

    I work as I.T technician in Suez University, Egypt, and my second job in Flexo plates and I need large films for that, I have absolutely no knowledge about chemicals.

    I need someone to explain to me how to prepare Kodak DK-50.

    As the attached photo I can prepare the Kodak DK-50 & Kodak Replenisher DK-50R, the problem as you can see in the subject title "Sodium Metaborate"

    I found the below page here, but can't understand it well

    https://www.largeformatphotography.i...ium-metaborate

    From user IanG


    10g Sodium Metaborate can be substituted by 7g Borax (sodium Tetraborate) and 1.5g Sodium, that's the recommendation from Kodak in a Datebook for DK50

    If you want a more accurate substitution then:


    10% Solution Sodium Metaborate

    14.5 grams Sodium hydroxide
    69 grams Borax (Tetraborate)
    Water to make 1 liter.


    Some books have an incorrect substitution, Kodalk is Sodium Metaborate (Octahydrate) which is why the total weight of Borax & Hydroxide is slightly less than the equivalent amount of Kodalk.

    But I still don't understand how to prepare sodium metaborate alternative

    I prepare 1 liter of Kodak DK-50 & Kodak Replenisher DK-50R

    So I want the simple way and quantity to prepare sodium metaborate alternative for 1 liter of DK-50 & Kodak Replenisher DK-50R.

    Thank you every one, sorry for my bad English

    Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574

  2. #2

    Re: Please help "Sodium Metaborate" alternative

    Quote Originally Posted by mohamed.yusif View Post
    Hello every one,

    Good day to you all,
    I have a big problem and I need help, I have been using Kodak DK-50 for a while now and I can't get any new supplies from it, I tried to get some from outside Egypt and the airport customs in Egypt blocked it from entering the country, right now I can't work and me and my family depend on my work.

    I work as I.T technician in Suez University, Egypt, and my second job in Flexo plates and I need large films for that, I have absolutely no knowledge about chemicals.

    I need someone to explain to me how to prepare Kodak DK-50.

    As the attached photo I can prepare the Kodak DK-50 & Kodak Replenisher DK-50R, the problem as you can see in the subject title "Sodium Metaborate"

    I found the below page here, but can't understand it well

    https://www.largeformatphotography.i...ium-metaborate

    From user IanG


    10g Sodium Metaborate can be substituted by 7g Borax (sodium Tetraborate) and 1.5g Sodium, that's the recommendation from Kodak in a Datebook for DK50

    If you want a more accurate substitution then:


    10% Solution Sodium Metaborate

    14.5 grams Sodium hydroxide
    69 grams Borax (Tetraborate)
    Water to make 1 liter.


    Some books have an incorrect substitution, Kodalk is Sodium Metaborate (Octahydrate) which is why the total weight of Borax & Hydroxide is slightly less than the equivalent amount of Kodalk.

    But I still don't understand how to prepare sodium metaborate alternative

    I prepare 1 liter of Kodak DK-50 & Kodak Replenisher DK-50R

    So I want the simple way and quantity to prepare sodium metaborate alternative for 1 liter of DK-50 & Kodak Replenisher DK-50R.

    Thank you every one, sorry for my bad English

    Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574Click image for larger version. 

Name:	Kodak DK-50 New.jpg 
Views:	23 
Size:	63.9 KB 
ID:	188574
    Jacobson & Jacobson ("Developing," 18th revised Edition, 1972 p. 88) state that two parts by weight of Kodalk are the equivalent of one part of weight of carbonate in normal developers. Sodium carbonate should work in DK-50 and DK-50R. The amount will vary according to the form of sodium carbonate used (e.g., anhydrous vs. mono-hydrated).

    N. Riley
    http://normanrileyphotography.com

  3. #3

    Join Date
    Sep 1998
    Location
    Oregon now (formerly Austria)
    Posts
    3,404

    Re: Please help "Sodium Metaborate" alternative

    DK-50 is quite similar to D-76 in characteristics. Maybe you could source D-76 where you are as a substitute. If not, you might try playing with a sodium carbonate/sodium bicarbonate buffer. Start by substituting half the weight of sodium carbonate for the metaborate in the original formula and add to that sodium bicarbonate (baking soda). You might want to start with 1/3 the weight of the carbonate and then add more or less from there till you get the results you are looking for.

    For other ways of creating a buffering system without the metaborate, look here: https://books.google.com/books?id=qU...bonate&f=false

    Hope that helps a bit,

    Doremus

  4. #4

    Join Date
    May 2017
    Posts
    16

    Re: Please help "Sodium Metaborate" alternative

    You can use the 10% sodium metaborate formula that you cite. However you will have to make changes to DK-50 and DK-50R accordingly to account for use of 10% solution rather than the solid sodium metaborate in the original recipe.

    For DK-50, 10 gm sodium metaborate will translate to 100 ml of the solution. Instead of 500 ml starting amount of water, use 400 ml.

    For DK-50R, 40 gm sodium metaborate = 400 ml of the solution. Start with 350 ml water here instead of the 750 ml.

    Everything else remains the same.
    Last edited by nmp; 12-Mar-2019 at 03:41.

  5. #5

    Join Date
    Mar 2019
    Location
    Egypt, Suez
    Posts
    4

    Re: Please help "Sodium Metaborate" alternative

    Thanks NER

  6. #6

    Join Date
    Mar 2019
    Location
    Egypt, Suez
    Posts
    4

    Re: Please help "Sodium Metaborate" alternative

    Thanks Doremus Scudder

  7. #7

    Join Date
    Mar 2019
    Location
    Egypt, Suez
    Posts
    4

    Re: Please help "Sodium Metaborate" alternative

    Thanks nmp

Similar Threads

  1. Borax (sodium tetraborate) SUBSTITUTE for sodium metaborate?
    By kev curry in forum Darkroom: Film, Processing & Printing
    Replies: 9
    Last Post: 12-May-2014, 17:37
  2. Clarification needed re "Odorless" Fixer vs Standard Sodium Thiosulfate Fixers
    By G Benaim in forum Darkroom: Film, Processing & Printing
    Replies: 1
    Last Post: 30-Jun-2011, 02:44
  3. Sodium Thiosulfate "Plain Fixer" question
    By atlcruiser in forum Darkroom: Film, Processing & Printing
    Replies: 32
    Last Post: 19-May-2011, 10:22
  4. sodium metaborate in PMK - octa or tetra?
    By splanken in forum Darkroom: Film, Processing & Printing
    Replies: 6
    Last Post: 5-Nov-2008, 12:56

Bookmarks

Posting Permissions

  • You may not post new threads
  • You may not post replies
  • You may not post attachments
  • You may not edit your posts
  •