Steven, Multi-Exposure has an effect in very dense areas, specially those from 3.0D to 3.4D (in a V850).
Portra is a film "for prints" (and today for scanners) that makes the job by building moderate densities and it may benefit slightly from M-E in the extreme highlights (high density in the negative).
To see the Multi-Exposure effect one has to see what happens with slides sporting deep shadows. Slides medium is designed to be projected, in that case it's worth building such extreme densities to obtain a breathtaking static contrast.
Portra it's an easy to scan film, first because information is encoded in the negative with lower densities (than slides), and second because it was re-engineered to have larger (overlaping) color clouds to optimize result when it was scanned in digital minilabs.
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Inversions:
C-41 film should be inverted (adjusted) manually, here Tim Parkin explains why:
http://www.drumscanning.co.uk/about/colour-negatives/
https://web.archive.org/web/20180430...our-negatives/
Fuji ColorKit, as stated in the link, delivers nice inversions, but if wanting to also adjusting it manually then I see no benefit from doing it with the SF or Epson Scan standard inversions.
Ps has powerful tools to manage color, and if wanting more then we have 3D Lut Creator for total control.
Having those tools, the weak link in the chain is only the operator, he requires skills and having an aesthetic criterion to bring the look to the point he (or a customer) wants.
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