Original Photo (slightly underexposed) scanned in on a V700:



Camera (nikon) set to VIVID, negative placed so that light shines on it just right from behind:



(That was a different negative, but the set up was the same)

Photoshop Elements:
Lighten Shadow about 7 percent
Midtone Contrast about +75 Percent
Raise left (Dark) slider on levels to taste
Decrease saturation to taste