I mix my own Pyrocat HD a gallon at a time (in my backyard or in my open door garage with breathing protection) with distilled water and keep it in amber bottles and even though I process a lot of sheet film, it still takes me 12-18 months to use up the developer and have never experienced any loss in effectiveness with oxidation for which the glycol option is considered the operational "hedge". IMHO Pyrocat HD is easy to mix which concurrently makes it the least expensive developer to use with only the basics of lab equipment needed. Mix this chemistry yourself as well as all of your other photographic chemicals and purchase film and photographic paper with the savings.
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