I do a lot of stitching, which in general is not that much work and generates very high quality results. But for someone who wants to "scan artwork in the most professional way possible", I will agree with Drew and state that this is not a good way to go. Even if you are shifting horizontally and vertically (as opposed to rotating), your rig would have to be exactly parallel to the artwork, be exactly level, have a perfectly linear lens with zero barrel/pincushion distortion, and shift exactly parallel to the artwork to avoid awkward overlaps of adjacent images which would create the need for creative PS work to correct. thereby destroying any semblance of faithfulness to the artwork.
Additionally, I have a D800e, which generates files of about 7320 pixels on the long side. If you want to print at 300 dpi, and not interpolate, you will be limited to artwork no larger than 24" on the long side (unless you resort to stitching). A 5D would mean even smaller art work.
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